yeah theres no way to get the wep key from the wep screen in windows. (well im sure some hacker somewhere has a way but theres no direct way to do so)
So we were just showing him how to reset it so he could recreate a key
your could sniff around the wireless and hope that you pick up initial traffic of the handshake between the router and machine. Then youll have to decrypt the 64/128 bit encryption.